Many Body Aspects on the Lattice Vibrational Properties of Germanene and Silicene along Highly Symmetry Directions

Abstract

The investigation of lattice vibrational properties in monolayer two-dimensional honeycomb lattices comprising 2D group-IV semiconductor materials such as Germanene and Silicene (Low Buckled structure) holds immense significance in the realm of research, owing to their potential integration into the forthcoming electronic sector for information technology. The ductile nature of 2D group-IV semiconductor materials enables seamless integration with existing semiconductor technology on substrates, setting them apart from Graphene. Our primary objective revolves around comprehending the lattice vibrational properties of Germanene and Silicene (LB) through the examination of their honeycomb and buckled lattice structures. We use the Adiabatic Bond Charge Model with a Python program to derive vibrational frequencies at the Г points along highly symmetrical directions. Moreover, we extensively analyze the acoustical and optical contributions to the lattice vibrational frequencies. We anticipate that the phonon frequencies along the Г‒M direction for 2D atomically thin Germanene and Silicene will yield reasonably similar outcomes to those other research groups achieve.